Radical Chain-Growth Polymerization
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Clicking on the donut icon will load a page at altmetric. Find more information on the Altmetric Attention Score and how the score is calculated. Efficient radical cyclopolymerization was achieved through systematic optimization of the electronic properties of 1,6-diene structures.
The ability of 1,6-diene-fused allylic sulfone to undergo efficient SO 2 extrusion generated a propagating alkyl radical capable of reversible deactivation. This strategy provides a general platform for the synthesis of polymers incorporating complex main-chain structures and degradable functionalities. Complete synthetic experiments, optimization tables, experimental methods, and additional experimental data PDF.
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